Comparing (a) and (b), which of the following statements is correct?
A
(b) is more acidic than (a)
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B
Conjugate base of (b) is stabilised by hydrogen bonding
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C
(a) is more acidic than (b)
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D
None of the above
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Solution
The correct option is C (a) is more acidic than (b) Comparing (a) and (b):
The conjugate base of A is more stable as compared to the conjugate base of B since H-bonding stabilises the anion in the former one.
Compound (b) does not form H-bonding so it is least acidic compare to (a).