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Question

Comparing (a) and (b), which of the following statements is correct?

A
(b) is more acidic than (a)
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B
Conjugate base of (b) is stabilised by hydrogen bonding
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C
(a) is more acidic than (b)
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D
None of the above
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Solution

The correct option is C (a) is more acidic than (b)
Comparing (a) and (b):
The conjugate base of A is more stable as compared to the conjugate base of B since H-bonding stabilises the anion in the former one.

Compound (b) does not form H-bonding so it is least acidic compare to (a).

Hence, statement (c) is correct.

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