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Question

Complete the following reactions:
(i) CH3COOHNH3−−Δ(A)Br2/KOH−−−−−(B)HNO2−−−(C)
(ii) CH3NH2(A)CH3OH(B)CH3I.

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Solution

(i) CH3COOHNH3−−ΔCH3CONH2 (A) AcetamideBr2/KOH−−−−−−−−−−−−−−−−−Hoffmann bromide degradationCH3NH2 (B) methyl amine HNO2−−−CH3OH methanol +CH3ON=O methyl nitrite +CH3OCH3 dimethyl ether
(ii) CH3NH2HNO2−−−CH3OHPI3CH3I.

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