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Question

Complete the reactions by matching List-I with List-II.

List-IList-ll
A) 2Na2S2O3+I2Δ 1) Photographic complex Ag2S2O3
B) Na2S2O3+dil.HCl2) Ag2S+NaBr
C) Na2S2O3+AgNO33) NaCl+SO2+S+H2O
D) Na2S2O3+AgBr4) Na2S4O6+2NaI
The correct match is:

A
(A)-2, (B)-1, (C)- 4, (D)-3
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B
(A)-1, (B)-2, (C)- 3, (D)-4
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C
(A)-3, (B)-4, (C)- 2, (D)-1
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D
(A)-4, (B)-3, (C)- 1, (D)-2
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Solution

The correct option is D (A)-4, (B)-3, (C)- 1, (D)-2
A) 2Na2S2O3+I2Na2S4O6+2NaI In this reaction, sodium thiosulphate acts as a reducing agent and reduces Iodine.
(B)Na2S2O3+dil.HaNaCl+SO2+S+H2O
(C)Na2S2O3+AgNO3Ag2S2O3
complex compound used in photographic films.
(D)Na2S2O3+AgBrAg2S+NaBr

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