Question

Question 36
Components of a binary mixture of two liquids A and B were being separated by distillation. After some time separation of components stopped and composition of vapour phase became same as that of liquid phase. Both the components started coming in the distiliate. Explain why this happened?

Answer 1

Both the components are appearing in the disiliate and composition of liquid and vapour is same. This shows that liquids have formed azeotropic mixture and boils at constnat temperature hence cannot be separated at this stage by distillation or fractional distillation. Solution having azeotropic nature show large positive or negative deviation from Raoult's law depending upon intermolecular interaction.