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Question

Compound 'A' on chlorination gives compound 'B', compound 'B' reacts with alc. KOH gives gas 'C', which decolourizes Baeyer's reagent and ozonolysis of compound 'C' gives only HCHO compound. Then compound 'A' is:

A
C2H6
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B
C2H4
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C
C4H10
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D
C2H5Cl
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Solution

The correct option is A C2H6
The compound A is ethylene C2H6.
It on chlorination gives compound B which is ethyl chloride.

C2H6Achlorination−−−−−−C2H5ClB

On dehydrohalogenation with alc. KOH, ethyl chloride gives ethylene (gas C).
C2H5ClBCH2=CH2C

Ethylene decolourizes Baeyer reagent.
C2H4+H2O+[O]CH2OHCH2OH

Ozonolysis of ethylene gives formaldehyde.
CH2=CH2Ozonolysis−−−−−2HCHO.

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