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Question

Compound which has the highest pKa is:
[0.77 Mark]

A
HF
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B
HCl
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C
HBr
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D
HI
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Solution

The correct option is A HF
We know that, more is the acidic strength, lesser is the pKa value and oppositely lesser is the acidic strength more is the pKa value. The acidic strength increases in the order HF<HCl<HBr<HI since bond dissociation energy decreases in this order. Thus HF has the highest pKa value.

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