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Question

Compound with molecular formula C3H6O can show:

A
Both positional isomerism and metamerism
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B
Metamerism
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C
Positional isomerism
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D
Functional group isomerism
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Solution

The correct option is D Functional group isomerism
For a compound with molecular formula CcHhXxNnOo
Degree of unsaturation=(c+1)h2x2+n2
Where, X = Halogen
c=number of carbon atom
h=number of hydrogen atom
n=number of nitrogen atom
o=number of oxygen atom
In C3H6O
Degree of unsaturation=(3+1)62=1
Degree of unsaturation=1

No possible metamerism and positional isomers are possible.

Possible function group isomers are
CH3CH2CH=O & CH3COCH3. Therefore, functional group isomerism is the most appropriate.

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