Vant Hoff's Equation and Effect of Temperature on Equilibrium Constant
Concentration...
Question
Concentrations of two reactants A and B are 0.8molL−1 each. On mixing the two, the reaction sets in at a slow rate to form C and D. A+B⇌C+D At equilibrium, concentration of C was found to be 0.60molL−1. Calculate the equilibrium constant.
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Solution
The initial concentrations of A and B are 0.8 M each. The equilibrium concentration of C is 0.60 M. Thus, 0.60 M of A will react with 0.60 M of B to form 0.60 M of C and 0.60 M of D. 0.80−0.60=0.20 M of A and 0.80−0.60=0.20 M of B will remain at equilibrium. The equilibrium constant Kc=[C][D][A][B] Kc=0.60×0.600.20×0.20 Kc=9