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Question

Concentrations of two reactants A and B are 0.8molL1 each. On mixing the two, the reaction sets in at a slow rate to form C and D.
A+BC+D
At equilibrium, concentration of C was found to be 0.60molL1. Calculate the equilibrium constant.

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Solution

The initial concentrations of A and B are 0.8 M each. The equilibrium
concentration of C is 0.60 M.
Thus, 0.60 M of A will react with 0.60 M of B to form 0.60 M of C and 0.60
M of D.
0.800.60=0.20 M of A and 0.800.60=0.20 M of B will remain at equilibrium.
The equilibrium constant
Kc=[C][D][A][B]
Kc=0.60×0.600.20×0.20
Kc=9

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