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Question

Consider a body centered cubic (BCC) arrangement, let de,dfd,dbd be the distances between successive atoms located along the edge, the face-diagonal, the body diagonal respectively in a unit cell. Their order is given by

A
dbd>de>dfd
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B
de<dfd<dbd
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C
dfd>dbd>de
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D
dbd>dfd>de
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Solution

The correct option is D dbd>dfd>de
The edge length of the unit cell is de. The structure of cubic unit cell is shown below.

The length of face diagonal is dfd
Thus, in ABC
AC2=AB2+BC2d2fd=d2e+d2ed2fd=2d2edfd=de2

The length of body diagonal is dbd
In AEF
AE2=AF2+EF2d2bd=d2e+2d2ed2bd=3d2edbd=de3

Thus,
dbd>dfd>de

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