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Question

Consider a cyclic process ABCA performed by a sample of 2 moles of an ideal gas as shown in figure. If the net heat transfer during the cyclic process is -1200 J, the work done during the process BC
(Take R=8.314 J\mol-K)


A
-3324.4 J
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B
-4526 J
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C
-6520 J
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D
+4526 J
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Solution

The correct option is B -4526 J
Given:Qnet=1200J,TA=300K,TB=500K,n=2moles

Since, it is a cyclic process,

Qnet=Wnet

WAB+WBC+WCA=1200

WBC=1200WABWCA

Now,WCA=0,

Since it is a constant volume process.

WBC=1200WAB

Now, line AB passes through origin,

T=KV

500=KV2

300=KV1

K(V2V1)=200

Now,WAB=V1V2pdv

Also, PV=n¯RT

P=n¯RKVV=n¯RK

WAB=V1V2n¯RKdV=n¯RK(V2V1)=2×8.314×200=3325.6J

WBC=12003325.6=4525.6J

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