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Question

Consider an isolated system and process as shown in the figure. (Process is that Seeta sitting on the freely movable piston jumps out). Assume no effect of reaction force due to jump on the system. Pressure equivalent of piston is 9 atm and the pressure equivalent when Seeta is on the piston is 10 atm. Atmospheric pressure is 1 atm. (given molar heat capacity at constant volume CV=3 Cal mol1 K1 )


Final temperature of the system in state - 2 is:

A
200 K
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B
40022/sCal/K
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C
320C
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D
47C
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Solution

The correct option is D 47C

Process is adiabatic and irreversible as the expansion is sudden, against a constant pressure of 10 atm(p2)

By the first law of Thermodynamics

nCv(T2T1)=w=p2(v2v1)

nCv(T2T1)=p2[nRT2P2nRT1P1]

3(T2T1)=10[RT210RT120]

3(T2T1)=[2T2T1]

5T2=4T1

T2=45T1 T2=45×400=320 K=47C


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