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Question

Consider structures I to VII and answer the following questions.
Identify the pairs of compounds that represent position isomerism.
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Solution

Ans. In position isomerism, two or more compounds differ in the position of substituent, functional group or multiple bonds but molecular formula is same. In the given structures, 1 and II, III and IV, and VI and VII are position isomers.
I. CH3CH2CH2CH2OH and
II. CH3CH2CH(OH)CH3 are position isomers.
Ill. CH3C(CH3)(OH)CH3 and
IV. CH3CH(CH3)CH2OH are position isomers.
VI. CH3OCH2CH2CH3 and
VII. CH3OCH(CH3)CH3 are position isomers.

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