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Question

Consider the below shown reaction.:
Ag2S+NaCN(A)
(A)+Zn(B)
If (B) is a metal, then (A) and (B) are, respectively:

A
Na2[Zn(CN)4] and Zn
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B
Na[Ag(CN)2] and Ag
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C
Na2[Ag(CN)4] and Ag
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D
Na3[Ag(CN)4] and Ag
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Solution

The correct option is A Na[Ag(CN)2] and Ag
Consider the below shown reactions:
Ag2S+NaCN(A)

(A)+Zn(B)

If (B) is a metal, then (A) and (B) are Na[Ag(CN)2] and Ag respectively

Ag2S+4NaCN2Na[Ag(CN)2](A)+Na2S

2Na[Ag(CN)2](A)+ZnNa2[Zn(CN)4]Sodium tetracyano zincate (II)+2Ag(B)
Option B is correct.

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