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Byju's Answer
Standard XII
Chemistry
Nucleophilic Substitution in Alkyl Halides
Consider the ...
Question
Consider the compounds (I) R-I (II) R-Br ; (III) R-Cl ; (IV)R-F . The rate of
S
N
2
reaction is:
A
I>II>III>IV
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B
II>I>III>IV
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C
I=II=III=IV
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D
IV>III>II>I
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Solution
The correct option is
A
I>II>III>IV
S
N
2
reaction,nucteophilic attack from back side.The rate of
S
N
2
reaction depend on the learning group. Rate of reaction increases with good leading group.the order of leading group is
I
−
>
B
r
−
>
C
l
−
>
F
−
So rate increases as
R
−
I
>
R
−
B
r
>
R
−
C
l
>
R
−
F
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Similar questions
Q.
Give the decreasing order of hyperconjugative effect of
′
R
′
in
R
−
C
H
=
C
H
2
, where
′
R
′
is:
I.
M
e
−
II.
E
t
−
III.
M
e
2
C
H
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IV.
M
e
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Q.
Give the decreasing order of hyperconjugative effect of R in
R
−
C
H
=
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H
2
,
where R is:
I.
M
e
II.
E
t
III.
M
e
2
C
H
IV.
M
e
3
C
Q.
Arrange these compounds in order of increasing S
N
1 reaction rate:
Q.
The decreasing order of acidity of the following compounds is:
Q.
The increasing order of the rate of
H
C
N
addition to compounds I - IV is:
I.
H
C
H
O
II.
C
H
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C
O
C
H
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III.
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Standard XII Chemistry
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