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Question

Consider the equilibrium:

HgO(s)+4I(aq)+H2O(l)HgI24(aq)+20H(aq)
Which changes will decrease the equilibrium concentration of HgI24?

A
Addition of 0.1 M HI (aq.)
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B
Addition of HgO (s)
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C
Addition of H2O (l)
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D
Addition of KOH (aq.)
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Solution

The correct options are
C Addition of H2O (l)
D Addition of KOH (aq.)
Addition of water will result in dilution. It will decrease the concentration of all the species.
Addition of hydroxide ion will shift the equilibrium to left so that more and more hydroxide ions will react to nullify the effect of increased hydroxide ion concentration.
In both these cases, the equilibrium concentration of Hgl24 will decrease.

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