Consider the equilibrium reactions, H3PO4⇌K1H++H2PO−4 H2PO4⇌K1H++HPO−24 H−2PO4⇌K1H++HPO−34 The equilbrium constant, K for the following dissociation H3PO4⇌3H++PO−34 is
A
K1/K2K3
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B
K1K2K3
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C
K2/K1K3
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D
K1+K2+K3
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Solution
The correct option is BK1K2K3 K1=[H+][H2PO−4][H3PO4],K2=[H+][HPO2−4][H3PO−4],K3=[H+][PO3−4][H2PO−4]