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Question

Consider the following Baeyer-Villiger oxidation.
Which statement(s) is/are correct?

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A
EWG in peracid facilitates the reaction.
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B
Strong ¯e-donating group migrates.
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C
The migrating group order is 3alkyl>Phenyl>H>23alkyl>I3alkyl>Me.
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D
The migrating group order of substituted phenyl group is pAnisyl>pTolyl>ph>pChlorophenyl>pnitrophenyl
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Solution

The correct option is A EWG in peracid facilitates the reaction.
The Baeyer-Villiger oxidation of acetophenone gives phenol and acetic acid.
Electron withdrawing group in peracid facilitates the reaction.

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