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Question

Consider the following bromides: The correct order of SN1 reactivity is:

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A
B>C>A
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B
B>A>C
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C
C>B>A
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D
A>B>C
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Solution

The correct option is D B>C>A
In B, the carbocation formed is resonance stabiised. So this is the most reactive compound.
In C, the carbocation formed is 2o. In A, the carbocation formed is 1o. Therefore, C is more stable than A. So, the order is B>C>A.

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