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Question

Consider the following isomerism:
(i) Ionization (ii) Hydrate (iii) Coordination (iv) Geometrical (v) Optical
Which of the above isomerisms are exhibited by [Cr(NH3)2(OH)2Cl2]−?

A
(i) and (v)
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B
(ii) and (iii)
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C
(iii), (ii) and (i)
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D
(iv) and (v)
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Solution

The correct option is D (iv) and (v)
The complex [Cr(NH3)2(OH)2Cl2 exhibits geometrical isomerism. Two geometrical isomers are cis and trans isomers.
It contains no element of symmetry and is optically active.
It can be resolved into d form and l form.

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