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Question

Consider the following list of reagents: Acidified K2Cr2O7, alkaline KMnO4, CuSO4, H2O2, Cl2, O3, FeCl3 and Na2S2O3. The total number of reagents that can oxidise aqueous iodide to iodine is:

A
7
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B
6
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C
5
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D
4
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Solution

The correct option is B 6
K2Cr2O7+7H2SO4+6KI4K2SO4+Cr(SO4)3+3I2+7H2O

2CuSO4+4KICu2I2+I2+2K2SO4

H2O2+2KII2+2KOH

Cl2+2KI2KCl+I2

O3+2KI+H2O2KOH+I2+O2

2FeCl3+2KI2FeCl2+I2+2KCl

2KMnO4+KI+H2OKIO3+2MnO2+2KOH
Na2S2O3 reacts with I2 to form iodide.
There are 6 such reactions in which oxidise aqueous iodide is converted into iodine and KMnO4 cannot.

Hence, the correct option is B.

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