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Byju's Answer
Standard XII
Chemistry
Thermodynamic Processes
Consider the ...
Question
Consider the following reaction:
C
O
(
g
)
+
1
2
O
2
(
g
)
→
C
O
2
(
g
)
How are
△
E and
△
H related for the reaction?
A
△
H =
△
E - 0.5 RT
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B
△
H =
△
E - RT
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C
△
H =
△
E + 0.5 RT
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D
△
H =
△
E - 1.5 RT
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Solution
The correct option is
D
△
H =
△
E - 0.5 RT
g
= -0.5
Δ
H
=$\Delta E
\Delta H
=
\Delta E
+
\Delta n_g$RT
$\Delta n
$ -0.5RT
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For the reaction
N
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H
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Δ
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Q.
Assume that the temperature remains essentially constant in the upper part of the atmosphere. Obtain an expression for the variation of pressure in the upper atmosphere with height. (The mean molecular weight of air is
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Q.
For the reaction
C
O
(
g
)
+
(
1
/
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O
2
(
g
)
⇌
C
O
2
(
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,
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Q.
Tollen's reagent is used for the detection of aldehyde when a solution of
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g
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3
is added to glucose with
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H
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O
H
then fluconic acid is formced
A
g
+
+
e
−
→
A
g
;
E
o
r
e
d
=
0.8
V
C
6
H
12
O
6
+
H
2
O
→
C
6
H
12
O
7
(Gluconic acid)
+
2
H
+
+
2
e
−
;
E
o
r
e
d
=
−
0.05
V
A
g
(
N
H
3
)
2
+
e
−
→
A
g
(
s
)
+
2
N
H
3
;
(Use
2.202
×
R
T
F
=
0.0592
and
F
R
T
=
38.92
at
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)
2
A
g
+
+
C
6
H
22
O
6
+
H
2
O
→
2
A
g
(
s
)
+
C
6
H
212
O
7
+
2
H
+
Find
ln
K
of this reaction?
Q.
Assertion :In the following reaction:
C
(
s
)
+
O
2
(
g
)
⟶
C
O
2
(
g
)
;
Δ
H
=
Δ
U
−
R
T
Reason:
Δ
H
is related to
Δ
U
by the equation,
Δ
H
=
Δ
U
−
n
g
R
T
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