Consider the following reaction sequence- CH3C - CH HgSO 4 aq-H 2 SO 4 - A Heat PCl 5 - BThe products A and B are- respectively -

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Oxidation of Alcohols

Consider the ...

Question

Consider the following reaction sequence,
$C H_{3} C \equiv C H a q . H_{2} S O_{4} ⟶ H g S O_{4} A P C l_{5} ⟶ H e a t B$
The products $(A)$ and $(B)$ are, respectively :

C H_{3} C O C H_{3}

and

C H_{3} C C l_{2} C H_{3}

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C H_{3} C H_{2} C H O

and

C H_{3} C H_{2} C H C l_{2}

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C H_{3} C H O H C H_{3}

and

C H_{3} C H C l C H_{3}

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C H_{3} C H_{2} C H_{2} O H

and

C H_{3} C H_{2} C H_{2} C l

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{C H}_{3} C \equiv C H 2 m o l e - ---- \to H C l A H e a t - ---- \to a q . K O H B

{C H}_{2} = {C H}_{2} c o l d - ------ \to d i l . {K M n O}_{4} A e x c e s s - --- \to {P C l}_{5} B

(A)

(B)

{C H}_{2} = {C H}_{2} c o l d - -------- \to d i l . K M n O_{4} A e x c e s s - --- \to P C I_{s} B

P h C H (C H_{3})_{2} O_{2} - - \to H v A

A a q . H_{2} S O_{4} - ----- \to warm B + C

(A)

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