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Question

Consider the following reactions & identify A, X, Y & Z


A

A-Methoxymethane, X-Ethanol, Y-Ethanoic acid, Z -Semicarbazide

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B

A-Ethanal, X-Ethanol, Y-But-2-enal, Z -Semicarbazone

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C

A-Ethanol, X-Acetaldehyde, Y-Butanone, Z-Hydrazone

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D

A-Methoxymethane, X-Ethanoic acid, Y-Acetate ion, Z-Hydrazine

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Solution

The correct option is B

A-Ethanal, X-Ethanol, Y-But-2-enal, Z -Semicarbazone


C2H6O could be dimethyl ether, ethylene oxide or ethanol. But the reaction with Cu at 573 K all but confirms that the substrate is in fact, ethanol C2H5OH, which gets oxidized by cupper dust to ethanol. So A is ethanal (A), which shows a positive Tollen’s reagent test.

A - acetaldehyde, undergoes aldol condensation to yield but-2-enal - the αβ unsaturated aldehyde. Also, A reacts with semicarbazide to give an imine called - semicarbazone (this is not a specific compound, it is a class of imine).


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