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Question

Consider the following reactions. In which case the formation of product is favoured by decrease in pressure?
(1) CO2(g)+C(s)2CO(g); ΔH=+172.5 kJ
(2) N2(g)+3H2(g)2NH3(g); ΔH=91.8 kJ
(3) N2(g)+O2(g)2NO(g); ΔH=+181 kJ
(4) 2H2O(g)2H2(g)+O2(g);ΔH=484.6 kJ

A
2,3
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B
3,4
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C
2,4
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D
1,4
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Solution

The correct option is D 1,4
If pressure is decreased, then equilibrium shift to more gas molecules side.
Here product is favoured if product gas mole are more than reactant gas mole.
(1) CO2(g)+C(s)2CO
Here reactant gas mole= 1
Product gas moles= 2
If we reduce pressure, equilibrium shift to product side.
(4) 2H2O(g)2H2(g)+O2(g)
Reactant gas moles= 2
Product gas moles= 3
If we reduce pressure, equilibrium shift to product side

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