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Pericyclic Reaction

Consider the ...

Question

Consider the following reactions:

Which of these reactions are possible?

A and D

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B and D

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B, C and D

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A and B

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Solution

The correct option is B B and D
Aryl halides, due to the partial double bond character generated by chlorine, aryl cation is not formed.

Vinyl halides do not give Friedel-Crafts reaction, because the intermediate that is generated (vinyl cation) is not stable.

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(C H_{3})_{3} C C H (O H) C H_{3} conc. H_{2} S O_{4} - ------ \to

(C H_{3})_{2} C H C H (B r) C H_{3} alc. K O H - ---- \to

(C H_{3})_{2} C H C H (B r) C H_{3} (C H_{3})_{3} O^{-} K^{+} - ------- \to

Which of these reaction(s) will not produce Saytzeff product?

∠ A O B

≅

d_{A}

d_{B}

d_{A}

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d_{B}

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