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Solubility Product

Consider the ...

Question

Consider the following salts:
$N a C l, H g C l_{2}, H g_{2} C l_{2}, C u C l_{2}, C u C l$ and $A g C l .$ Identify the correct set of insoluble salts in water.

H g_{2} C l_{2}, C u C l, A g C l

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H g C l_{2}, C u C l, A g C l

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H g_{2} C l_{2}, C u C l_{2}, A g C l

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H g_{2} C l_{2}, C u C l, N a C l

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Solution

The correct option is A $H g_{2} C l_{2}, C u C l, A g C l$
$H g_{2} C l_{2}, C u C l, A g C l$ are insoluble in water due to high lattice enthalpy and low hydration enthalpy.
$N a C l, H g C l_{2}, C u C l_{2}$ are soluble in water due to low lattice enthalpy and high hydration enthalpy.

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H g_{2} C l_{2}, A g C l, P b C l_{2}

C u C l

Which of the following metal chloride gives white ppt and black ppt respectively with aequeous solution of gas (B)

P b c l_{2} a n d p b C l_{4}

K_{2} C_{2} O_{4}

H g C l_{2}

2 H g C l_{2} + K_{2} C_{2} O_{4} \to 2 K C l + 2 C O_{2} + H g_{2} C l_{2}

H g_{2} C l_{2}

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