Consider the following species: N3–,O2–,F–,Na+,Mg2+andAl3+
(B) Arrange them in the order of increasing ionic radii.
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Solution
Ionic radii
The ionic radii of isoelectronic species increase with a decrease in the magnitude of nuclear charge. The arrangement of the given species in order of their increasing nuclear charge is as follow:
SpeciesN3–<O2–<F–<Na+<Mg2+<Al3+
Nuclear +7+8+9+11+12+13
Charge
Therefore, the arrangement of given species in order of their increasing ionic radii is as follow: Al3+<Mg2+<Na+<F−<O2−<N3−
Final answer:
(a) Number of electrons in all the given species =10
Hence these ions are all isoelectronic.
(b) Increasing order of ionic radii is Al3+<Mg2+<Na+<F−<O2−<N3−