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Question

Consider the following species: N3,O2,F,Na+,Mg2+ and Al3+

(B) Arrange them in the order of increasing ionic radii.

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Solution

Ionic radii

The ionic radii of isoelectronic species increase with a decrease in the magnitude of nuclear charge. The arrangement of the given species in order of their increasing nuclear charge is as follow:

Species N3< O2 < F < Na+ < Mg2+ < Al3+

Nuclear +7 +8 +9 +11 +12 +13
Charge


Therefore, the arrangement of given species in order of their increasing ionic radii is as follow: Al3+<Mg2+<Na+<F<O2<N3

Final answer:

(a) Number of electrons in all the given species =10
Hence these ions are all isoelectronic.

(b) Increasing order of ionic radii is Al3+<Mg2+<Na+<F<O2<N3

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