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Question

Consider the following statements are arrange in the order of true/false as given in the codes. Select the correct arrangement.
S1: Ammonia on heating with concentrated solution of sodium hypochlorite gives nitrogen gas.
S2: The phosphine gas dissolves in water in presence of sunlight and produces phosphonium hydroxide like ammonium hydroxides.
S3: Barium azide on heating gives pure nitrogen gas.
S4: The oxo-acids of phosphorus in which phosphorus has lower oxidation state less than +5 contain either P−P or P−H bonds but not both in addition to P=O and P−OH bonds.

A
T F T T
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B
F F T T
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C
T T T F
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D
T F T F
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Solution

The correct option is A T F T T
S1: Ammonia on heating with concentrated NaOCl gives Nitrogen gas that is reduction reaction.
S2: Phosphine gas does not dissove in water.
S3: Pure nitrogen gas is prepared on heating Barium azide (Ba3N2)
S4: Oxo-acids of phosphorus with lower oxidation states contain either PP or PH bonds only.

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