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Question

Consider the following structures:

What is the relation between x and y?

A
x=y
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B
x>y
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C
x<y
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D
None is true
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Solution

The correct option is B x>y

x and y represents the CO bond length. x is greater than y because in the later one, lone pair is delocalising over two carbonyl groups and thus is less available for either of one which makes CO bond length short.

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