Consider the reaction:
4NO2(g) + O2(g) → 2N2O5(g), ΔrH = −111kJ. If N2O5(s) is formed instead of N2O5(g) in the above reaction, the ΔrH value will be:
(given, ΔH of sublimation for N2O5 is 54 kJ mol−1)
ΔrH = −111 kJ
−111 − 54 = ΔH′
ΔH′ = −165 kJ