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Question

Consider the reaction of HCl with the following compounds
Propene(I); methyl-vinyl ether(II); vinyl chloride(III) and cis-2-butene(IV). The increasing order reactivity towards addition reaction will be _______.

A
I<II<III<IV
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B
I<II<IV<III
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C
III<I<IV<II
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D
IV<III<II<I
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Solution

The correct option is B III<I<IV<II
(I) propene carbocation CH3CH+CH3 (stable by electron donating character of of two CH3 groups.
(IV) CIS-2-butene carbocation CH3CH+CH2CH3 (stable by electron donating character of of two CH3 and CH2CH3 groups.
So order of reactivity is same as stability of carbocation
III<I<IV<II

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