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Question

Consider the reaction of water with F2 and suggest, in terms of oxidation and reduction, which species are oxidized/reduced.

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Solution

The reaction between fluorine and water can be represented as:
2F2(g)+2H2O(l)4H+(aq)+4F(aq)+O2(g)
This is an example of a redox reaction as water is getting oxidized to oxygen, while fluorine is being reduced to fluoride ion.
The oxidation numbers of various species can be represented as:

Fluorine is reduced from zero to (-1) oxidation state. A decrease in oxidation state indicates the reduction of fluorine.
Water is oxidized from (- 2) to zero oxidation state. An increase in oxidation state indicates
oxidation of water.


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