Consider the spectral line resulting from the transition n=2→n=1 in the atoms and ions given below. The shortest wavelength is produced by
A
hydrogen atom
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B
deuterium atom
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C
singly ionized Helium
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D
doubly ionised Lithium
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Solution
The correct option is D doubly ionised Lithium We know that, 1λ=RZ2[1n22−1n21]⇒1λαZ2 λ is shortest when 1λ is largest i.e., when Z is big. Z is highest for lithium.