Consider the two gaseous equilibrium involving SO2 and the corresponding equilibrium constant at 299KSO2(g)+1/2O2(g)⇌SO3(g);K1 4SO3(g)⇌4SO2(g)+2O2(g);K2
The value of the equilibrium constant are related by :
K1=(SO3)(SO2)(O2)1/2⇒K2=(SO2)4(O2)2(SO3)4=1(K1)4
K2=1(K1)4