Considering bohr's model to be valid for lithium atom, Energy associated with its valency electron can be given for various transitions. This valency electrons of 1st orbit. [Neglect energy of electrons of 1st orbit]
(P)Energy of atom in ground state.(1)−3.4 ev(q)Energy of photon released in transition from.2nd excited state to ground state.(2)−13.6 ev(r)Energy of 1st excited state.(3)12.1 ev(s)sonization energy of valency electron.(4)13.6 ev