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Standard XII
Chemistry
Entropy
Considering e...
Question
Considering entropy (S) as a thermodynamic parameter what is the criterion for the spontaneity of any process?
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Solution
According to entropy as a thermodynamic parameter,
Spontaneous process
Δ
S
>
0
Non-spontaneous process
Δ
S
<
0
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Assertion :The thermodynamic factor which determines the spontaneity of a process is the free energy. For a process to be spontaneous the free energy must be -ve Reason: The change in free energy is related to the change in enthalpy and change in entropy. The change in entropy for a process must always be positive if it is spontaneous.
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