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Question

Considering only inductive effect, which of the following statements is correct?




A
(a) is more stable than (b).
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B
(a) is less stable than (b).
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C
Both (a) and (b) are equally stable.
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D
Nothing can be said about stability.
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Solution

The correct option is A (a) is more stable than (b).

Fluorine is an electron withdrawing group , so it shows I effect.
In case (a), fluorine is attached to the first carbon, whereas in case (b) , fluorine is attached to second carbon.
More is the distance , less is the I strength.
So, I strength in case (a) is higher than (b)
Electron withdrawing group when attached to carbanion increases the stability .
So, (a) is more stable than (b)

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