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Question

Considering the elements F, Cl, O and N the correct order of their chemical reactivity in terms of oxidizing property is:
(a) F > Cl > O > N (b) F > O > Cl > N
(c) Cl > F > O > N (d) O > F > N > Cl

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Solution

In a period, from left to right, with an increase in the atomic number, the oxidizing character increases due to the presence of vacant d orbitals in their valence shells.
Hence, the decreasing order of oxidizing character is F > O > N.
On moving down the group, the oxidizing character decreases. hence, F > Cl.
But O has higher oxidizing character than Cl thus, O > Cl.
Thus, the correct order of chemical reactivity of F, Cl, O, and N in terms of their oxidizing property is F > O > Cl > N.

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