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Question

Considering the elements F,Cl,O and S, the correct order of their electron affinity values is:

A
F>Cl>O>S
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B
F>O>Cl>S
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C
Cl>F>S>O
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D
O>F>S>Cl
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Solution

The correct option is C Cl>F>S>O
Electron gain enthalpy increases as we move from left to right in a periodic table because effective nuclear charge increases, so F,Cl have more electron gain enthalpy than O and S.
Fluorine and oxygen have the smallest size in their respective groups. In case of fluorine, valence shell electronic configuration is 2s22p5. On adding another electron to the valence shell, it causes severe electron-electron repulsion due to which system becomes comparatively unstable. The same happens in case of oxygen. So, electron gain enthalpy of Cl>F and S>O.
Therefore, correct order is: Cl>F>S>O

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