Oxidation of ferrous ions
In electrochemical series on going top to bottom the ease of oxidation decreases.
In this series, the substance is at the top, is more reactive, and gets oxidized easily than the substance that is at the bottom of the series.
This means the substance which is having high reduction potential than ferrou ions can easily oxidize ferrous ions to ferric ions.
The elements like Cl2,Br2 andAu of the table can oxidize ferrous ions.
E∘Fe3+|Fe2+=0.771 V
Cl2(g)+2e−→2Cl−(aq):E∘=1.36
Br2(g)+2e−→2Br−(aq):E∘=1.09
Au3+(g)+3e−→Au(s):E∘=1.40