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Question
Conversion of esters to aldehydes can be accomplished by:
Conversion of esters to aldehydes can be accomplished by:
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Solution
The correct option is A Reduction with diisobutyl aluminium hydride
Conversion of esters to aldehydes can be accomplished by reduction with diisobutyl aluminium hydride.
CH3(CH2)9−O||C−O−C2H5DIBAL−H→H2OCH3(CH2)9−CHO.Conversion of esters to alcohols can be accomplished by reduction with lithium aluminium hydride.Stephen reduction involves the preparation of aldehydes. Nitriles react with anhydrous stannous chloride in presence of dry hydrogen chloride gas followed by their hydrolysis to form aldehydes.
Rosenmund reduction is the catalytic hydrogenation of acid chlorides to aldehydes.
Diisobutyl aluminium hydride is used to reduce α−βunsaturated esters to the corresponding allylic alcohols.
Conversion of esters to aldehydes can be accomplished by reduction with diisobutyl aluminium hydride.
CH3(CH2)9−O||C−O−C2H5DIBAL−H→H2OCH3(CH2)9−CHO.
Conversion of esters to alcohols can be accomplished by reduction with lithium aluminium hydride.
Stephen reduction involves the preparation of aldehydes. Nitriles react with anhydrous stannous chloride in presence of dry hydrogen chloride gas followed by their hydrolysis to form aldehydes.Rosenmund reduction is the catalytic hydrogenation of acid chlorides to aldehydes.
Diisobutyl aluminium hydride is used to reduce α−βunsaturated esters to the corresponding allylic alcohols.
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