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Question

Conversion of phenol to salicylic acid and to salicyaldehyde are known as? (respectively)

A
Reimer - Tiemann reaction and Kolbe's reaction
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B
Williamson's synthesis and Hydroboration-oxidation
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C
Kolbe's reaction and Williamson's synthesis
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D
Kolbe's reaction and Reimer - Tiemann reaction
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Solution

The correct option is D Kolbe's reaction and Reimer - Tiemann reaction
Phenol on reaction with carbon dioxide in the presence of a base like NaOH gives Salicylic acid. It is Kolbe's Reaction
Phenol on reaction with chloroform in the presence of a base like NaOH gives Salicylaldehyde. It is Reimer-Tiemann reaction.
Both are shown in the figure.

934394_937891_ans_2de867aea75f4a2d965910fb5a874a0c.png

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