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Nomenclature of Alcohols

Converti 3-Me...

Question

Convert

(i) 3-Methylaniline into 3-nitrotoluene.

(ii) Aniline into 1,3,5-tribromobenzene.

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Solution

(i)

(ii)

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Q. Give one chemical test to distinguish between Aniline and N-methylaniline.

Q. Give one chemical test to distinguish between the following pairs of compounds.
(i) Methylamine and dimethylamine

(ii) Secondary and tertiary amines

(iii) Ethylamine and aniline

(iv) Aniline and benzylamine
(v) Aniline and N-methylaniline.

How will you convert?

(i) Benzene into aniline

(ii) Benzene into N, N-dimethylaniline

(iii) Cl−(CH₂)₄−Cl into hexan-1, 6-diamine?

Q. Aniline and N-methylaniline cannot be distinguished by azo dye test
If this is true enter 1, if false enter 0.

Q. (a) Illustrate the following reactions giving suitable example in each case :
(i) Hoffmann bromaimide degradation reaction
(ii) Diazotisation
(iii) Gabriel phthalimide synthesis

(b) Distinguish between the following pairs of compounds :
(i) Aniline and N-methylaniline

(i i) (C H_{3})_{2} N H

(C H_{3})_{3} N

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