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Question

Copper forms two oxides following law of variable proportions. One gram of each oxide in hydrogen gas gave 0.799g and 0.888g of the metal respectively. Give the composition of these oxides.

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Solution

Let the two oxides of Cu be named A and B
oxide A
mass of Cu in 1g of oxide A = 0.888g
mass of O in 1g of oxide A =1-0.888=0.112g
oxide B
mass of Cu in 1g of oxide B = 0.799g
mass of O in g of oxide B = 1-0.799=0.201g
In oxide A , 1g Cu is combined with oxygen = 0.112 x 1/0.888 = 0.126g
In oxide B , 1g Cu is combined with oxygen = 0.201 x 1/0.799 = 0.252g
the different weight of oxygen combined with a fixed weight (1g) of Cu are in ratio 0.126: 0.252 or 1: 2
This is a simple whole ratio that shows the agreement with the law of multiple properties.

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