Core metal of chlorophyll is
Structure of chl-a look like tadpole.
It has Porphyrin head and phytol tail.
Porphyrin head- Size is 15X15A0. It is hydrophilic and acidic in nature. Its a tetrapyrole structure. Mg is a core metal held by 2 coordinate and 2 covalent bonds.
Phytol tail- Size is 20A0 long. It is hydrophobic and alcoholic in nature. Tail remain embedded in lipid bilayer of thylakoid membrane.
So, the correct answer is 'Mg'.