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Question

Correct combination among the following is
i) Water can be converted into vapour at 1000C only
ii) Vapour pressure can be increased more than the atmospheric pressure at a certain temperature.
iii) Lowering of vapour pressure is directly proportional to mole fraction of solute.

A
All are correct
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B
ii only wrong
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C
iii only correct
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D
All are wrong
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Solution

The correct option is B iii only correct
Using clausius clapeyron equation,
we get logP2P1=ΔHR×(1T11T2)
Therefore, at any particluar temperature, the vapour pressure of solution is unique.
Also, conversion to vapour of a liquid can take place at many temperatures and many pressure values.
The third statement is the outcome of Raoult's law.

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