The correct option is A ψw=ψs
Free energy is potential to do work and the free energy of water is ‘water potential' (ψw).
ψw=ψs+ψp, where
ψs = solute potential
ψp = pressure potential
A plasmolysed cell is flaccid and the turgor pressure (pressure potential) of such a cell is zero.
∴ψw=ψs