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Bond Length

Correct order...

Question

Correct order of increasing $C - O$ bond length of $C O, C O_{3}^{2 -}, C O_{2}$ is:

A

C O_{3}^{2 -} < C O_{2} < C O

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B

C O_{2} < C O_{3}^{2 -} < C O

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C

C O < C O_{3}^{2 -} < C O_{2}

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D

C O < C O_{2} < C O_{3}^{2 -}

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Solution

The correct option is D $C O < C O_{2} < C O_{3}^{2 -}$
$B o n d l e n g t h α \frac{1}{B o n d o r d e r}$
Bond orders of the given compounds are:
$C O = 3, C O_{2} = 2.3, C O_{3}^{- 2} = 1.33$
So the correct order of Bond lengths $C O < C O_{2} < C O_{3}^{- 2}$
Hence, option $D$ is correct.

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