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Byju's Answer
Standard XII
Chemistry
Reactivity with Halogens (Group 1)
Correct relat...
Question
Correct relationship between pairing energy
(
P
)
and C.F.S.E.
(
Δ
0
)
in complex ion
[
I
r
(
H
2
O
)
6
]
3
+
isk
A
Δ
o
<
P
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B
Δ
o
>
P
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C
Δ
o
=
P
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D
Cannot comment
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Solution
The correct option is
A
Δ
o
<
P
Water is a weak filed ligand. The crystal field splitting caused by water is small. Hence,
Δ
o
<
P
.
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Similar questions
Q.
In complexes of weak field ligands,
Δ
o
<
P
(pairing energy), the energy difference between
t
2
g
and
e
g
sets is relatively less. Under the influence of strong field ligands,
Δ
o
>
P
(pairing energy), the energy difference between
t
2
g
and
e
g
sets is relatively high.
The correct statement regarding
[
C
r
(
e
n
)
2
C
l
2
]
+
and
[
C
o
(
C
2
O
4
)
2
(
N
H
3
)
2
]
−
complex ions is
:
Q.
Given the following binding energies:
1.
17
8
O
→
131
M
e
V
2.
56
26
F
e
→
493
M
e
V
3.
238
92
U
→
1804
M
e
V
Compare the binding energies per nucleon
(
Δ
=
B
A
)
of the three nuclei.
Q.
Which of the following pairs of complex ions has higher value of
Δ
o
and why?
[
C
o
(
N
H
3
)
6
]
3
+
a
n
d
[
R
h
(
N
H
3
)
6
]
3
+
Q.
Which of the following pairs of complex ions has higher value of
Δ
o
and why ?
[
F
e
(
C
2
O
4
)
3
]
4
−
a
n
d
[
F
e
(
C
2
O
4
)
3
]
3
−
Q.
What is CFSE of complex ion
[
F
e
F
6
]
4
−
in terms of
Δ
o
?
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